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Todd N. Whittaker
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Controlling activity and selectivity using water in the Au-catalysed preferential oxidation of CO in H 2
J Saavedra, T Whittaker, Z Chen, CJ Pursell, RM Rioux, BD Chandler
Nature Chemistry 8 (6), 584-589, 2016
2042016
H2 Oxidation over Supported Au Nanoparticle Catalysts: Evidence for Heterolytic H2 Activation at the Metal–Support Interface
T Whittaker, KBS Kumar, C Peterson, MN Pollock, LC Grabow, ...
Journal of the American Chemical Society 140 (48), 16469-16487, 2018
1262018
Water Poisons H2 Activation at the Au–TiO2 Interface by Slowing Proton and Electron Transfer between Au and Titania
KB Sravan Kumar, TN Whittaker, C Peterson, LC Grabow, BD Chandler
Journal of the American Chemical Society 142 (12), 5760-5772, 2020
432020
Supported Ni–Au Colloid Precursors for Active, Selective, and Stable Alkyne Partial Hydrogenation Catalysts
JE Bruno, NS Dwarica, TN Whittaker, ER Hand, CS Guzman IV, ...
ACS Catalysis 10 (4), 2565-2580, 2020
312020
Combining Benzyl Alcohol Oxidation Saturation Kinetics and Hammett Studies as Mechanistic Tools for Examining Supported Metal Catalysts
A Mahdavi-Shakib, J Sempel, L Babb, A Oza, M Hoffman, TN Whittaker, ...
ACS Catalysis 10 (17), 10207-10215, 2020
272020
Kinetics of H2 Adsorption at the Metal–Support Interface of Au/TiO2 Catalysts Probed by Broad Background IR Absorbance
A Mahdavi‐Shakib, KBS Kumar, TN Whittaker, T Xie, LC Grabow, ...
Angewandte Chemie 133 (14), 7814-7822, 2021
252021
Hydrogen Adsorption at the Au/TiO2 Interface: Quantitative Determination and Spectroscopic Signature of the Reactive Interface Hydroxyl Groups at the Active Site
A Mahdavi-Shakib, LC Rich, TN Whittaker, BD Chandler
ACS Catalysis 11 (24), 15194-15202, 2021
172021
The role of surface hydroxyls in the entropy-driven adsorption and spillover of H2 on Au/TiO2 catalysts
A Mahdavi-Shakib, TN Whittaker, TY Yun, KB Sravan Kumar, LC Rich, ...
Nature Catalysis 6 (8), 710-719, 2023
132023
Physisorbed H2O on Metal-Oxide Supported Au Nanoparticle Catalysts: Origin of the Poisoning Effect in H2 Oxidation
T Whittaker, KB Sravan Kumar, LC Grabow, BD Chandler
North American Catalysis Society NAM 26, 2019
2019
H2 and O2 Activation over Au Catalysts: Heterolytic H2 Activation at the Metal-Support Interface and the Role of Support Protons
T Whittaker, BD Chandler, KB Sravan Kumar, RM Rioux, LC Grabow
North American Catalysis Society NAM 26, 2019
2019
Understanding the Role of H2O in H2 Activation on Metal-Oxide Supported Au
T Whittaker, CL Peterson, KB Sravan Kumar, MN Pollock, LC Grabow, ...
27th Organic Reactions Catalysis Society Meeting, 2018
2018
Understanding the Role of H2O in the Preferential Oxidation of CO in H2: H2 Oxidation Kinetics and H2 and CO Adsorption
T Whittaker, MN Pollock, CL Peterson, J Saavedra, CJ Pursell, ...
North American Catalysis Society NAM 25, 2017
2017
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