| Surface Investigation and Morphological Analysis of Structurally Disordered MgCl2 and MgCl2/TiCl4 Ziegler–Natta Catalysts M D’Amore, KS Thushara, A Piovano, M Causa, S Bordiga, E Groppo ACS Catalysis 6 (9), 5786-5796, 2016 | 90 | 2016 |
| Quantitative structural determination of active sites from in situ and operando XANES spectra: From standard ab initio simulations to chemometric and machine learning approaches AA Guda, SA Guda, KA Lomachenko, MA Soldatov, IA Pankin, ... Catalysis Today 336, 3-21, 2019 | 82 | 2019 |
| The active sites in the Phillips catalysts: origins of a lively debate and a vision for the future E Groppo, GA Martino, A Piovano, C Barzan ACS Catalysis 8 (11), 10846-10863, 2018 | 55 | 2018 |
| Ligands Make the Difference! Molecular Insights into CrVI/SiO2 Phillips Catalyst during Ethylene Polymerization C Barzan, A Piovano, L Braglia, GA Martino, C Lamberti, S Bordiga, ... Journal of the American Chemical Society 139 (47), 17064-17073, 2017 | 54 | 2017 |
| Electronic properties of Ti sites in Ziegler–Natta catalysts A Piovano, M Signorile, L Braglia, P Torelli, A Martini, T Wada, G Takasao, ... ACS Catalysis 11 (15), 9949-9961, 2021 | 38 | 2021 |
| Revisiting the identity of δ-MgCl2: Part I. Structural disorder studied by synchrotron X-ray total scattering T Wada, G Takasao, A Piovano, M D'Amore, A Thakur, P Chammingkwan, ... Journal of catalysis 385, 76-86, 2020 | 38 | 2020 |
| Spectroscopic Evidences for TiCl4/Donor Complexes on the Surface of MgCl2-Supported Ziegler–Natta Catalysts A Piovano, M D’Amore, KS Thushara, E Groppo The Journal of Physical Chemistry C 122 (10), 5615-5626, 2018 | 38 | 2018 |
| Flexible ligands in heterogeneous catalysts for olefin polymerization: Insights from spectroscopy A Piovano, E Groppo Coordination Chemistry Reviews 451, 214258, 2022 | 36 | 2022 |
| Insights into Cr/SiO 2 catalysts during dehydrogenation of propane: an operando XAS investigation M Botavina, C Barzan, A Piovano, L Braglia, G Agostini, G Martra, ... Catalysis Science & Technology 7 (8), 1690-1700, 2017 | 33 | 2017 |
| Formation of highly active Ziegler–Natta catalysts clarified by a multifaceted characterization approach A Piovano, T Wada, A Amodio, G Takasao, T Ikeda, D Zhu, M Terano, ... ACS Catalysis 11 (22), 13782-13796, 2021 | 32 | 2021 |
| In Situ X- and Q-Band EPR Investigation of Ethylene Polymerization on Cr/SiO2 Phillips Catalyst E Morra, GA Martino, A Piovano, C Barzan, E Groppo, M Chiesa The Journal of Physical Chemistry C 122 (37), 21531-21536, 2018 | 28 | 2018 |
| Revisiting the identity of δ-MgCl2: Part II. Morphology and exposed surfaces studied by vibrational spectroscopies and DFT calculation A Piovano, M D'Amore, T Wada, PC Bruzzese, G Takasao, A Thakur, ... Journal of catalysis 387, 1-11, 2020 | 27 | 2020 |
| The influence of alcohols in driving the morphology of magnesium chloride nanocrystals KS Thushara, M D'Amore, A Piovano, S Bordiga, E Groppo ChemCatChem 9 (10), 1782-1787, 2017 | 25 | 2017 |
| Unraveling the Catalytic Synergy between Ti3+ and Al3+ Sites on a Chlorinated Al2O3: A Tandem Approach to Branched Polyethylene A Piovano, KS Thushara, E Morra, M Chiesa, E Groppo Angewandte Chemie International Edition 55 (37), 11203-11206, 2016 | 25 | 2016 |
| Tuning the Ti3+ and Al3+ Synergy in an Al2O3/TiClx Catalyst To Modulate the Grade of the Produced Polyethylene A Piovano, E Morra, M Chiesa, E Groppo ACS Catalysis 7 (8), 4915-4921, 2017 | 20 | 2017 |
| Photoinduced Ethylene Polymerization on the CrVI/SiO2 Phillips Catalyst L Mino, C Barzan, GA Martino, A Piovano, G Spoto, A Zecchina, E Groppo The Journal of Physical Chemistry C 123 (13), 8145-8152, 2018 | 19 | 2018 |
| Tracking the reasons for the peculiarity of Cr/Al2O3 catalyst in ethylene polymerization GA Martino, C Barzan, A Piovano, A Budnyk, E Groppo Journal of catalysis 357, 206-212, 2018 | 19 | 2018 |
| Disclosing the Interaction between Carbon Monoxide and Alkylated Ti3+ Species: a Direct Insight into Ziegler–Natta Catalysis A Piovano, J Zarupski, E Groppo The Journal of Physical Chemistry Letters 11 (14), 5632-5637, 2020 | 18 | 2020 |
| Rationalizing the Effect of Triethylaluminum on the Cr/SiO2 Phillips Catalysts GA Martino, A Piovano, C Barzan, J Rabeah, G Agostini, A Bruekner, ... Acs Catalysis 10 (4), 2694-2706, 2020 | 18 | 2020 |
| Genesis of MgCl2‐based Ziegler‐Natta Catalysts as Probed with Operando Spectroscopy A Piovano, P Pletcher, MEZ Velthoen, S Zanoni, SH Chung, K Bossers, ... ChemPhysChem 19 (20), 2662-2671, 2018 | 17 | 2018 |
