| Ab Initio Study of the Solvent Effects on the Singlet− Triplet Gap of Nitrenium Ions and Carbenes C Gonzalez, A Restrepo-Cossio, M Márquez, KB Wiberg, M De Rosa The Journal of Physical Chemistry A 102 (16), 2732-2738, 1998 | 57 | 1998 |
| Studies of the mechanism of chlorination of indoles. Detection of N-chloroindole and 3-chloro-3H-indole as intermediates M De Rosa, JL Triana Alonso The Journal of Organic Chemistry 43 (13), 2639-2643, 1978 | 39 | 1978 |
| First synthesis of 2-aminopyrrole and simple 1-substituted-2-aminopyrroles. Observation of fast proton exchange at C-5. M De Rosa, RP Issac, G Houghton Tetrahedron letters 36 (51), 9261-9264, 1995 | 35 | 1995 |
| Electronic and Steric Effects on the Mechanism of the Inverse Electron Demand Diels− Alder Reaction of 2-Aminopyrroles with 1, 3, 5-Triazines: Identification of Five … M De Rosa, D Arnold The Journal of Organic Chemistry 74 (1), 319-328, 2009 | 33 | 2009 |
| Chlorination of 2-methyl-and 2-phenylindole with sodium hypochlorite. Formation of intermediates and their reactions with alkaline methanol M De Rosa, L Carbognani, A Febres The Journal of Organic Chemistry 46 (10), 2054-2059, 1981 | 31 | 1981 |
| Chlorination of pyrrole. N-Chloropyrrole: formation and rearrangement to 2-and 3-chloropyrrole M De Rosa The Journal of Organic Chemistry 47 (6), 1008-1010, 1982 | 27 | 1982 |
| Effect of N-chloro structure and 1-substituent on. sigma.-substitution (addition-elimination) in pyrroles M De Rosa, G Cabrera Nieto, F Ferrer Gago The Journal of Organic Chemistry 54 (22), 5347-5350, 1989 | 24 | 1989 |
| Nitrous acid deamination of 1, 1-disubstituted aromatic hydrazines M De Rosa, P Haberfield The Journal of Organic Chemistry 46 (13), 2639-2643, 1981 | 24 | 1981 |
| Effect of halogen on the reaction of 1-methylpyrrole with N-haloimides. M De Rosa, GC Nieto Tetrahedron letters 29 (20), 2405-2408, 1988 | 20 | 1988 |
| Four Mechanisms in the Reactions of 3-Aminopyrrole with 1,3,5-Triazines: Inverse Electron Demand Diels–Alder Cycloadditions vs SNAr Reactions via … M De Rosa, D Arnold, D Hartline The Journal of Organic Chemistry 78 (17), 8614-8623, 2013 | 17 | 2013 |
| Pyrylium-mediated transformations of natural products. Part 1. Synthesis and hydrolysis of 4-(4-methoxy-3-sulphophenyl)-2, 6-bis-(4-sulphophenyl) pyrylium perchlorate: a new … AR Katritzky, M De Rosa, NE Grzeskowiak Journal of the Chemical Society, Perkin Transactions 2, 841-847, 1984 | 17 | 1984 |
| Pyrylium-mediated Transformations of Natural Products. Part 2. Reaction of 4-(4-methoxy-3-sulphophenyl)-2, 6-bis-(4-sulphophenyl) pyrylium Perchlorate with Primary Amines AR Katritzky, JL Mokrosz, M De Rosa Journal of the Chemical Society, Perkin Transactions 2, 849-855, 1984 | 15 | 1984 |
| Mechanism of the inverse-electron demand Diels–Alder reaction of 2-aminopyrroles with 1, 3, 5-triazines: detection of an intermediate and effect of added base and acid M De Rosa, D Arnold Tetrahedron Letters 48 (17), 2975-2977, 2007 | 14 | 2007 |
| Acid-catalyzed intermolecular rearrangement of N-chlorocarbazole M De Rosa, A Quesada P, DJ Dodsworth The Journal of Organic Chemistry 52 (2), 173-175, 1987 | 14 | 1987 |
| The preparation and characterization of some N-chloro-2-and N-chloro-4-pyridones AR Katritzky, GR Khan, DE Leahy, M De Rosa The Journal of Organic Chemistry 49 (25), 4784-4786, 1984 | 14 | 1984 |
| Effect of the leaving group on the reaction of 2-aminopyrroles with electron deficient heteroaromatic azadienes: substitution by addition–elimination versus cycloaddition M De Rosa, D Arnold Tetrahedron letters 48 (23), 3991-3994, 2007 | 13 | 2007 |
| The chlorination of indoles with aqueous sodium hypochlorite. Proof of the existence of an N-chloro intermediate M De Rosa Journal of the Chemical Society, Chemical Communications, 482-483, 1975 | 13 | 1975 |
| Aromaticity and Aminopyrroles: Desmotropy and Solution Tautomerism of 1H-Pyrrol-3-aminium and 1H-Pyrrol-3(2H)-iminium Cation: A Stable σ-Complex M De Rosa, D Arnold The Journal of Organic Chemistry 78 (3), 1107-1112, 2013 | 12 | 2013 |
| Effect of electron-withdrawing substituents on the inverse-electron demand Diels-Alder reaction of 2-aminopyrroles and 1, 3, 5-triazines M De Rosa, D Arnold, E Blythe, MS Farrell, T Seals, K Wills, M Medved Heterocyclic Communications 13 (2-3), 97-100, 2007 | 12 | 2007 |
| Effect of Bronsted Acids and Bases, and Lewis Acid (Sn2+) on the Regiochemistry of the Reaction of Amines with Trifluoromethyl-β-diketones: Reaction of 3-Aminopyrrole to Selectively … M De Rosa, D Arnold, D Hartline, L Truong, R Verner, T Wang, C Westin The Journal of Organic Chemistry 80 (24), 12288-12299, 2015 | 10 | 2015 |
